When you want to focus on what has changed or is different between one skillset and another you typically do something called differences training. This training takes into account that you know the basic functionality of something and spends the majority of its time showing you what is different between the two things.
Well here are links to PowerPoint based training that does just that – shows you what is different between Office 2003 and Office 2010 to help you either get up to speed or decide to make the move from the older version of Office to the latest edition.
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Word – http://office.microsoft.com/en-us/word-help/make-the-switch-to-word-2010-RZ101816356.aspx
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Excel – http://office.microsoft.com/en-us/excel-help/make-the-switch-to-excel-2010-RZ101809963.aspx?CTT=5&origin=HA010370218
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PowerPoint – http://office.microsoft.com/en-us/powerpoint-help/make-the-switch-to-powerpoint-2010-RZ101791923.aspx?CTT=5&origin=HA010359435
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Outlook – http://office.microsoft.com/en-us/outlook-help/make-the-switch-to-outlook-2010-RZ101809884.aspx?CTT=5&origin=HA010370219
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Access – http://office.microsoft.com/en-us/access-help/make-the-switch-to-access-2010-RZ101791922.aspx?CTT=5&origin=HA010341722
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OneNote – http://office.microsoft.com/en-us/onenote-help/make-the-switch-to-onenote-2010-RZ101805102.aspx?CTT=1
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Visio – http://office.microsoft.com/en-us/visio-help/make-the-switch-to-visio-2010-RZ101850566.aspx?CTT=1